If you want ThrottleStop to start up with Windows 7 or Windows Vista then add it to the Task Scheduler. This example shows me adding RealTemp but you can also use this method to add ThrottleStop to the Task Scheduler.
Open up Task Scheduler and start by clicking on Create Basic Task... on the right hand side.

Enter a name for the task, ThrottleStop, and then click on Next.

For Trigger, choose the option, When I log on.

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